Niobium
Original source: Filella, M., May, P.M., 2020. The aqueous solution thermodynamics of niobium under conditions of environmental and biological interest. Applied Geochemistry 122, 104729.
Best stability constant values for niobium species, 25 °C and I 0 mol L-1:
Reaction |
log K |
Nb(OH)5(am.,s) = Nb(OH)50 |
–7.510 |
Nb2O5(s) + 5 H2O = 2 Nb(OH)50 |
–18.31 |
Nb(OH)50 + H+ = Nb(OH)4+ + H2O |
1.603 |
Nb(OH)50 + H2O = Nb(OH)6– + H+ |
–4.951 |
Nb6O198– + H+ = HNb6O197– |
14.95 |
HNb6O197– + H+ = H2Nb6O196– |
13.23 |
H2Nb6O196– + H+ = H3Nb6O195– |
11.73 |
HNa7Nb6O19 ·5H2O(s) = 7 Na+ + HNb6O19 |
11.85 |
References
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