Germanium

Original source: Filella, M., May, P.M., 2023. The aqueous solution chemistry of germanium under conditions of environmental and biological interest: Inorganic ligands. Applied Geochemistry 155, 105631.

Best stability constant values for germanium species, 25 °C and I 0 mol L-1:

Reaction log K
Ge(OH)4 + 2 e- = Ge2+ + 4H2O -7.206
GeO2(OH)22– + H+ = GeO(OH)3– 12.76
GeO(OH)3– + H+ = Ge(OH)4 9.099
8 Ge(OH)4 + 3 OH- = Ge8(OH)353- 28.33
GeO2(hexag,s) + 2 H2O = Ge(OH)4 –1.373
GeO2(tetra,s) + 2 H2O = Ge(OH)4 –4.999
Ge(OH)4 + 4 H+ + 6 F- = GeF62- + 4 H2O 27.98
Ge(OH)4 + 5 H+ + 6 F- = GeHF6- + 4 H2O 28.80
Ge(OH)4 + 4 H+ + 4 F- = GeF4 + 4 H2O 20.14
Ge(OH)4 + 3 H+ + 4 F- = GeF4(OH)- + 3 H2O 19.08
Ge(OH)4 + 3 H+ + 2 F- = GeF2(OH)- + 3 H2O 9.345

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