[Critical IUPAC publication of equilibrium data] [NBS Tables]
Critical IUPAC publication of solubility data
Historical
The IUPAC’s Solubility Data Series (SDS), begun in the mid-1970s, is an exhaustive compilation and critical evaluation of all the world’s published results of experimental determinations of solubility. It is not concerned chiefly with the assessment of equilibrium constants. However, solubility products and other equilibria are discussed depending on the chemical system in question.
Since 1979, over 70 SDS volumes have been published, including evaluated data on the solubility of gases in liquids, liquids in liquids, and solids in liquids. Since 1998, and following an agreement with NIST, the SDS compilations have been published four times a year in the Journal of Physical and Chemical Reference Data. Since January 2002, the Subcommittee on Solubility and Equilibrium Data (SSED) of the IUPAC Analytical Chemistry Division has continued the coordination of the SDS-related projects.
Scope
The IUPAC Solubility Data Project (SDP) has as its aim a comprehensive review of published data for solubilities of gases, liquids and solids in liquids or solids. A uniform format is followed for the assessment of all literature data sets. Where data from different sources agree sufficiently, recommended values are proposed. More information can be found at here (last update of data content 2012).
List of all references of interest for the reader.
| System | Reference |
|---|---|
| Scandium, yttrium, lanthanum and lanthanide nitrates | Siekierski et al. (1983) |
| Alkaline earth metal halates | Miyamoto et al. (1983) |
| Copper, silver, gold and zinc, cadmium, mercury oxides and hydroxides | Dirkse (1986) |
| Sulfites, selenites and tellurites | Masson et al. (1986) |
| Alkali metal orthophosphates | Eysseltova and Dirkse (1988) |
| Hydrogen sulfide, deuterium sulfide and hydrogen selenide | Fogg and Young (1988) |
| Copper and silver halates | Miyamoto et al. (1990) |
| Alkaline earth hydroxides in water and aqueous solutions | Lambert and Clever (1992) |
| Copper(I) halides and pseudohalides | Fritz and Koenigsberger (1996) |
| Ammonium phosphates | Eysseltova and Dirkse (1998) |
| Solubility of inorganic actinide compounds | Hála and Miyamoto (2007) |
| Rare earth metal chlorides in water and aqueous systems. Part 1. Scandium group (Sc, Y, La) | Mioduski et al. (2008) |
| Rare earth metal chlorides in water and aqueous systems. Part 2. Light lanthanides (Ce-Eu) | Mioduski et al. (2009) |
| Rare earth metal chlorides in water and aqueous systems. Part 3. Heavy lanthanides (Gd-Lu) | Mioduski et al. (2009) |
| Alkali metal nitrates. Part 1. Lithium nitrate | Eysseltová and Orlova (2010) |
| Metal carbonates. Part 1. Solubility and related thermodynamic quantities of cadmium(II) carbonate in aqueous systems | Gamsjäger et al. (2011) |
| Potassium sulfate in water | Eysseltová and Bouaziz (2012) |
| Rare earth metal iodides and bromides in water and aqueous systems. Part 1. Iodides | Mioduski et al. (2012) |
| Rare earth metal iodides and bromides in water and aqueous systems. Part 2. Bromides | Mioduski et al. (2013) |
| Alkaline earth carbonates in aqueous systems. Part 1. Introduction, Be and Mg | De Visscher et al. (2012) |
| Alkaline earth carbonates in aqueous systems. Part 2. Ca | De Visscher and Vanderdeelen (2012) |
| Rare earth metal fluorides in water and aqueous systems. Part 1. Scandium group (Sc, Y, La) | Mioduski et al. (2014) |
| Rare earth metal fluorides in water and aqueous systems. Part 2. Light lanthanides (Ce–Eu) | Mioduski et al. (2014) |
| Rare earth metal fluorides in water and aqueous systems. Part 3. Heavy lanthanides (Gd–Lu) | Mioduski et al. (2015) |
| Alkali metal nitrates. Part 2. Sodium nitrate | Eysseltová et al. (2017) |
| Lithium sulfate and its double salts in aqueous solutions | Sohr et al. (2017) |
Availability
The list of all solubility volumes is available here. The initial volumes (1 to 65, which corresponds to 1979-1996) were scanned by NIST into PDF files and digitized. Volumes 66-105 are available at the Journal of Physical and Chemical Reference Data and thus at a cost.